Gas exchange system flow configuration with thermally insulated sample chamber
Inventors
Johnson, Mark A. • Parr, Andrew S. • Eckles, Robert D.
Assignees
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Abstract
System flow path designs that minimize the impact of gas diffusion sources and sinks. By reducing the magnitude of parasitic sources and sinks, lower rates of photosynthesis and transpiration can be more accurately measured, e.g., without the need for extensive empirical compensation. The gas exchange analysis system includes a sample chamber having an inlet and an outlet, wherein the internal surface(s) of the chamber defining the measurement volume are metal plated. The system also typically includes a source of gas coupled with the inlet of the sample chamber, and a gas analyzer coupled with the outlet of the sample chamber and configured to measure a concentration of one or more gases exiting the chamber, whereby the metal plated internal surface(s) of the chamber reduces sorption of the one or more gases within the chamber.
Core Innovation
The invention provides a gas exchange analysis system for analyzing a sample using a sample chamber defining a measurement volume for analysis of a sample. The sample chamber has an inlet and an outlet, and the internal surface(s) of the chamber defining the measurement volume comprise a nickel plated plastic material. A source of gas is coupled with the inlet of the sample chamber, and a gas analyzer is coupled with the outlet of the sample chamber to measure a concentration of one or more gases exiting the chamber.
The system is configured so that the nickel plated internal surface(s) of the chamber reduce sorption of the one or more gases within the chamber. The disclosure also addresses accuracy by minimizing diffusion-driven parasitic gas sources and sinks via a sensor-head-proximal flow splitting configuration and reduced pneumatic path length.
The disclosure further describes thermally insulating sample chamber construction using direct digital manufacturing with plastic or composite materials, together with metal plating compatible with complex internal passages. The described implementation includes example experimental results using reduced CO2 concentration difference (Cs−Cr) with the head-proximal flow splitting and plated chamber surfaces.
Claims Coverage
The independent claim defines a gas exchange analysis system with a sample chamber whose internal measurement-volume surfaces are nickel plated plastic to reduce sorption of measured gases. Dependent claims refine the system by specifying the gas plumbing layout, the nickel plating approach, the plastic materials, the gases measured, the analyzer type, and representative sample types and alternative internal-surface material options.
Nickel plated plastic measurement-volume internal surfaces reduce sorption
A sample chamber defining a measurement volume for analysis of a sample, the sample chamber having an inlet and an outlet, wherein internal surface(s) of the chamber defining the measurement volume comprise a nickel plated plastic material, and the nickel plated internal surface(s) reduce sorption of the one or more gases within the chamber.
Gas source coupled to sample chamber inlet and gas analyzer coupled to sample chamber outlet
A source of gas coupled with the inlet of the sample chamber; and a gas analyzer coupled with the outlet of the sample chamber and configured to measure a concentration of one or more gases exiting the chamber.
Remote reservoir from the sample chamber
The system further comprises a reservoir positioned remotely from the sample chamber.
Electroless nickel plating of internal surfaces
The nickel plated internal surface(s) of the chamber are formed by electroless nickel plating on the internal surface(s).
Plastic material selected from nylon variants or ABS
The internal nickel plated plastic material comprises a plastic material selected from nylon, glass-filled nylon, or Acrylonitrile Butadiene Styrene (ABS).
Measured gases include CO2 and H2O
One or more gases measured by the gas analyzer include CO2 and H2O.
Infra-Red Gas Analyzer (IRGA) as the gas analyzer
The gas analyzer includes an Infra-Red Gas Analyzer (IRGA).
Across the claim set, the inventive focus is the use of nickel plated plastic internal measurement-volume surfaces in the sample chamber to reduce sorption of measured gases, combined with a coupled gas source and an outlet gas analyzer measuring gas concentration. Dependent claims further specify remote reservoir plumbing, electroless nickel plating, particular plastic substrates, CO2/H2O measurement, an IRGA gas analyzer, and related refinements.
Stated Advantages
Reduces sorption of one or more gases within the chamber.
Improves accuracy by reducing gas sorption and minimizing diffusion-driven parasitic gas sources and sinks (as reflected by reduced CO2 concentration difference (Cs−Cr) in example results).
Documented Applications
Gas exchange analysis for photosynthesis and transpiration using a sample chamber and a gas analyzer to measure gas concentrations exiting the chamber.
Use in an open photosynthesis system context, including measurement-volume sampling through a gas exchange analysis system.
Example experimental results for measuring CO2 concentration difference (Cs−Cr) in the described gas exchange analysis system.
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