Photoacoustic photon meter and process for measuring photon fluence
Inventors
Hwang, Jeeseong • Yung, Christopher • Briggman, Kimberly Ann • Lehman, John Henry
Assignees
United States Department of Commerce
Publication Number
US-11193914-B2
Publication Date
2021-12-07
Expiration Date
2040-01-28
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Abstract
A photoacoustic photon meter includes: a photoacoustic generative array including carbon nanotubes disposed in a photoacoustic generating pattern, such that the carbon nanotubes: receive photons comprising optical energy, and produce thermal energy from the optical energy; and a superstratum including a thermally expandable elastomer on which the photoacoustic generative array is fixedly disposed in position on the superstratum to spatially conserve the photoacoustic generating pattern, and such that the superstratum: is optically transparent to the photons; receives the thermal energy from the photoacoustic generative array; expands and contracts in response to receipt of the thermal energy; and produces photoacoustic pressure waves in response to the expansion and contraction, the photoacoustic pressure waves including a photoacoustic intensity and photoacoustic frequency that are based upon an amount of optical pressure applied to the carbon nanotubes by the photons, a spatial photon fluence of the photons, or a spectral photon fluence of photons.
Core Innovation
The invention disclosed is a photoacoustic photon meter comprising a photoacoustic generative array made of a plurality of carbon nanotubes disposed in a specific photoacoustic generating pattern. These carbon nanotubes receive photons containing optical energy and convert that optical energy into thermal energy. The array is fixedly disposed on a superstratum comprising a thermally expandable elastomer that is optically transparent to the photons. The superstratum receives the thermal energy, expands and contracts in response, producing photoacoustic pressure waves comprising intensity and frequency that depend on the optical energy applied, the spatial photon fluence, or the spectral photon fluence.
The problem solved addresses the limitations of conventional devices that fail to accurately measure local photon fluence in light-diffusing or light-absorbing materials, especially when the spatial distribution of scattering or absorbing entities is non-uniform and wavelength-dependent. Conventional sensors such as photomultipliers or photodiodes have issues with unknown reflectance, wavelength-dependent responsivity, and challenges embedding in bulk materials.
The photoacoustic photon meter overcomes these limitations by utilizing carbon nanotubes with known absorption coefficients arranged in desired patterns, which convert light energy into heat and subsequently into measurable photoacoustic pressure. The superstratum elastomer expands and contracts with the received thermal energy to generate photoacoustic pressure waves. The invention also encompasses processes for measuring photon fluence and local temperature rise, correlating photoacoustic signals to photon fluence quantitatively, and configurations that enable calibration of photoacoustic devices and multispectral measurements.
Claims Coverage
The patent includes three independent claims covering the apparatus and processes related to the photoacoustic photon meter.
Photoacoustic photon meter with carbon nanotube array and thermally expandable elastomer superstratum
The device comprises a photoacoustic generative array of carbon nanotubes arranged in a photoacoustic generating pattern that absorbs photons and produces thermal energy. This array is fixedly disposed on a superstratum made of thermally expandable elastomer which is optically transparent, receives thermal energy, expands and contracts to generate photoacoustic pressure waves. These pressure waves have intensity and frequency based on optical energy, spatial photon fluence, or spectral photon fluence applied to the carbon nanotubes.
Photoacoustic photon meter including photon propagation medium and transducer
The meter includes a photon propagation medium disposed on the superstratum, which receives and communicates the photoacoustic pressure waves. A photoacoustic transducer is in acoustic communication with the photon propagation medium and the superstratum, receiving photoacoustic pressure waves and producing electrical signals from which photon fluence can be determined.
Processes for measuring photon fluence and local temperature rise using the photoacoustic photon meter
Processes involve (1) receiving photons by the carbon nanotubes, producing thermal energy, expanding and contracting the superstratum to generate photoacoustic pressure waves used to measure photon fluence; and (2) measuring local temperature rise by detecting electrical resistance changes through electrical conductors in thermal contact with the carbon nanotubes under photon irradiation, producing current versus voltage curves, and obtaining temperature changes from temperature-dependent conductivity.
The independent claims cover the photoacoustic photon meter device comprising carbon nanotube arrays on a thermally expandable elastomer superstratum producing photoacoustic pressure waves corresponding to photon fluence, apparatus extensions involving photon propagation medium and transducers, and processes using the device to measure photon fluence and local temperature changes through electrical resistance measurements.
Stated Advantages
Accurate measurement of local photon fluence, temperature, and pressure in turbid or light-diffusing materials overcoming limitations of conventional sensors.
Ability to be embedded in bulk materials and provide spatially and spectrally resolved photon fluence measurements.
Provides calibration standards for photoacoustic imaging devices and quantitative multispectral optical measurements.
Offers simultaneous measurement of photoacoustic pressure and photon fluence for enhanced accuracy.
Enables measurement of local temperature rise via electrical resistance changes in carbon nanotubes.
Documented Applications
Local photon fluence measurement in turbid or optically diffusive media including biological tissues.
Calibration and performance testing of photoacoustic transducers and imaging devices.
Quantitative multispectral optical imaging including optical microscopy, optical coherence tomography, photoacoustic microscopy, and computed tomography.
Measurement of local temperature fluctuations during photothermal therapy applications.
Creation of resolution and fluence calibration targets for photoacoustic imaging systems.
Simultaneous measurement of photon fluence and photoacoustic pressure in media.
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